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            We report a rapid route to reclaim carbon fiber (CF) fabric and monomeric chemicals from amine-epoxy CF-reinforced polymer (CFRP) composites. We use a reaction that occurs in molten NaOH- KOH eutectic to selectively cleave aryl ether and amine linkages, which involves two temperature-dependant mechanisms. Bisphenol-A is isolated in up to quantitative yields, and recovered CF fabric is remanufactured into 2nd-generation CFRPs.more » « lessFree, publicly-accessible full text available December 2, 2025
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            Yu, Zehan; Lim, Y. Justin; Williams, Travis; Nutt, Steven (, Green Chemistry)We introduce an electrochemical approach to recycle carbon fiber (CF) fabrics from amine-epoxy carbon fiber-reinforced polymers (CFRPs). Our novel method utilizes a Kolbe-like mechanism to generate methyl radicals from CH 3 COOH to cleave C–N bonds within epoxy matrices via hydrogen atom abstraction. Recovered CFs are then remanufactured into CFRPs without resizing.more » « less
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            Lim, Y. Justin; Wong, Brandon; Macfee, Katie; Cueva, Alexa; Martinez, E. Aaron; Paxton, Cameron; Barnes, Robin; Kleinsasser, Eric; Williams, Travis J. (, Journal of Chemical Education)Most students enter college without any exposure to polymer science, which leads to the poor understanding and slow implementation of plastics recycling programs in the United States. To address the knowledge gap in chemical recycling, we introduce a 2-part laboratory experiment that was conducted in multiple high schools and public outreach events to demonstrate the depolymerization of PET via aminolysis and the remanufacturing of cleaved PET fragments into a new aramid polymer. Student experiences were evaluated with two post-lab assignments.more » « less
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